Formation of Complex XeHCl+ in the Xe+ + HCl Collision

Bulletin of the Korean chemical society

Jongbaik Ree¹  Yoo Hang Kim¹  Hyung Kyu Shin¹ 

关键词: Collision-induced complex;    XeHCl+;    Xe+;    HCl;   

DOI  :  

学科分类：化学（综合）

来源: Korean Chemical Society

【 摘 要 】

The formation of complex XeHCl⁺ in the collision-induced reaction of Xe⁺ with HCl has been studied by use of classical dynamics procedures using the London-Eyring-Polanyi-Sato empirical potential energy surfaces. A small fraction of trajectories on the Xe⁺ + HCl and Xe + HCl⁺ surfaces lead to the formation of complex XeHCl+ with life-times of 1-2 ps which is long enough to survive many rotations before redissociating back to the reactant state. The formation of complex XeHCl⁺ occurs mainly from collision angle of �? = 45�?.

【 授权许可】

Unknown