Asymmetric Ring Opening of Epoxides Catalyzed by Novel Heterobimetallic Schiff-Bases Containing Transition Metal Salts

Bulletin of the Korean chemical society

Rahul B Kawthekar¹  Geon-Joong Kim¹  Wen-tao Bi¹ 

关键词: Kinetic resolution;    Ring opening reactions;    Heterobimetallic catalyst;    Chiral intermediate;   

DOI  :  

学科分类：化学（综合）

来源: Korean Chemical Society

【 摘 要 】

An enantioselective ring opening of racemic terminal epoxides has been achieved by using heterobimetallic cobalt salen complexes with variety of nucleophiles. They were proven to be highly enantioselective and reactive for the synthesis of valuable chiral building blocks in enantio-riched forms up to 98% ee.

【 授权许可】

Unknown