Solvent-free Cyanosilylation of Carbonyl Compounds Catalyzed by NbCl5

Bulletin of the Korean chemical society

Soney C. George¹  Sung Soo Kim¹ 

关键词: Cyanohydrins;    Aldehydes;    Ketones;    Solvent-free;    NbCl5;   

DOI  :  

学科分类：化学（综合）

来源: Korean Chemical Society

【 摘 要 】

A simple and convenient method for the addition of TMSCN to carbonyl compounds is described. NbCl5 is found to possess a strong Lewis acid property to transform carbonyl compounds smoothly to the corresponding cyanosilylether in high yields (up to 99 %) in solvent- free conditions.

【 授权许可】

Unknown