期刊论文详细信息
Bulletin of the Korean chemical society | |
Cyanosilylation of Carbonyl Compounds Catalyzed by Potassium L-Aspartate | |
Soney C. George1  Sung Soo Kim1  Ho Sub Kim1  | |
关键词: Cyanohydrins; Aldehydes; Ketones; Potassium L-aspartate; | |
DOI : | |
学科分类:化学(综合) | |
来源: Korean Chemical Society | |
【 摘 要 】
Potassium L-aspartate has been used as a catalyst for the cyanosilylation of carbonyl compounds producing corresponding cyanohydrin trimethylsilyl ethers in excellent yield of up to 98%. Although the catalyst is chiral, the enantioselectivities observed are generally poor except for one case, �?-naphthaldehyde, 89% ee.
【 授权许可】
Unknown
【 预 览 】
Files | Size | Format | View |
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RO201912010240363ZK.pdf | 650KB | download |