Concise Synthesis of Biologically Interesting Mollugin and Its Analogues

Bulletin of the Korean chemical society

Jae Jin Shim¹  Do Hung Han¹  Yong Rok Lee¹  Byung Nam Kim¹  Yun Mi Kim¹  Xue Wang¹ 

关键词: Mollugin;    3;    4-Dihydromollugin;    Electrocyclization;    PhB(OH)2/AcOH;   

DOI  :  

学科分类：化学（综合）

来源: Korean Chemical Society

【 摘 要 】

The synthesis of naturally occurring mollugin and its analogues, 3,4-dihydromollugin, cis-3,4-dihydroxy-3,4- dihydromollugin, and trans-3,4-dihydroxy-3,4-dihydromollugin was achieved starting from 1,4-dihydroxynaphthalene- 2-carboxylic acid. The key reaction is an electrocyclization for pyranyl ring formation in the presence of PhB(OH)2/AcOH.

【 授权许可】

Unknown