Effect of Zn doping on optical properties and photoconductivity of SnS2 nanocrystalline thin films

Bulletin of materials science

M Karimipour²  R Etefagh³  N Shahtahmasebi¹ 

[1] Nano Research Centre, Ferdowsi University, Mashhad, Iran$$Nano Research Centre, Ferdowsi University, Mashhad, IranNano Research Centre, Ferdowsi University, Mashhad, Iran$$;Department of Physics, Faculty of Science, Vali-e-Asr Rafsanjan University, Rafsanjan, Iran$$Department of Physics, Faculty of Science, Vali-e-Asr Rafsanjan University, Rafsanjan, IranDepartment of Physics, Faculty of Science, Vali-e-Asr Rafsanjan University, Rafsanjan, Iran$$;Payame Nour University, Mashhad, Iran$$Payame Nour University, Mashhad, IranPayame Nour University, Mashhad, Iran$$

关键词: Thin film;    spray pyrolysis;    tin sulfide;    optical properties;    photoluminescence;    photoconductivity.;   

DOI  :  

学科分类：材料工程

来源: Indian Academy of Sciences

【 摘 要 】

Zn-doped SnS₂ thin films have been deposited simply by spray pyrolysis technique. The doping level was changed from [Zn/Sn] = 0 to 7.5 at%. The films were characterized by means of X-ray diffraction, scanning tunneling microscopy (STM), energy dispersive X-ray analysis (EDX), photoluminescence and UV-Vis spectroscopy. XRD patterns of the films with different zinc contents show that all samples have polycrystalline structure with Berndtite dominant phase and preferred orientation of (001) growth plane. Zn insertion causes a significant decrease in grain size. Optical bandgap of the films have been calculated for different dopant concentrations and they lie in the region of 2.3â€�??2.7 eV. Surprisingly, regardless of doping level, the luminescent properties of films are related to the fundamental bandgap energy and deep levels inside the bandgap. Photoconductivity of the films have been measured under visible light. Sensitivity to the light increases by zinc incorporation, which was a large amount for SnS₂:Zn of 7.5%.

【 授权许可】

Unknown