Gas-phase Basicity of Glycine

Croatica Chemica Acta

Bouchouxa, Guy¹  Chia, Ru Xuan² 

[1] Laboratoire des Mécanismes Réactionnels, Ecole Polytechnique, 91128 Palaiseau, France;a) Laboratoire des Mécanismes Réactionnels, Ecole Polytechnique, 91128 Palaiseau, France; b) bNanyang Technological University, 21 Nanyang Link, 637371 Singapore

关键词: proton affinity;    gas-phase basicity;    protonation entropy;    aminoacids;   

DOI  :  

学科分类：化学（综合）

来源: Croatica Chemica Acta

【 摘 要 】

The protonation thermochemistry of gaseous glycine is re-examined. The composite G3, G3MP2, G3B3, CBS-Q and CBS-QB3 methods have been used to estimate the enthalpy component i.e. the proton affinity of glycine, PA(Gly). The so called...

【 授权许可】

Unknown