Crystal structure of {[1′-(di­phenyl­phosphino)ferrocen­yl]meth­yl}di­methyl­ammonium chloride monohydrate

Acta Crystallographica Section E: Crystallographic Communications

Zá¹  branský¹ 

[1]Department of Inorganic Chemistry, Faculty of Science, Charles University, Hlavova 2030, 128 40 Prague 2, Czech Republic

关键词: CRYSTAL STRUCTURE;    FERROCENE;    AMINES;    PHOSPHINES;    STRUCTURE ELUCIDATION;   

DOI  :  10.1107/S2056989017013408

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

Individual ions and the solvating water mol­ecule constituting the structure of the title compound, [Fe(C8H13N)(C17H14P)]Cl·H2O, assemble into dimeric units located around crystallographic inversion centers via N—H⋯Cl and O—H⋯Cl hydrogen bonds. These discrete fragments are further inter­connected into chains by C—H⋯O inter­actions. The disubstituted ferrocene core in the {[1′-(di­phenyl­phosphino)ferrocen­yl]meth­yl}di­methyl­ammonium cation has an approximate synclinal eclipsed conformation and is tilted by 3.40 (11)°.

【 授权许可】

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