期刊论文详细信息
Acta Crystallographica Section E: Crystallographic Communications | |
Crystal structure of {[1′-(diphenylphosphino)ferrocenyl]methyl}dimethylammonium chloride monohydrate | |
Zá1  branský1  | |
[1]Department of Inorganic Chemistry, Faculty of Science, Charles University, Hlavova 2030, 128 40 Prague 2, Czech Republic | |
关键词: CRYSTAL STRUCTURE; FERROCENE; AMINES; PHOSPHINES; STRUCTURE ELUCIDATION; | |
DOI : 10.1107/S2056989017013408 | |
学科分类:数学(综合) | |
来源: International Union of Crystallography | |
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【 摘 要 】
Individual ions and the solvating water molecule constituting the structure of the title compound, [Fe(C8H13N)(C17H14P)]Cl·H2O, assemble into dimeric units located around crystallographic inversion centers via N—H⋯Cl and O—H⋯Cl hydrogen bonds. These discrete fragments are further interconnected into chains by C—H⋯O interactions. The disubstituted ferrocene core in the {[1′-(diphenylphosphino)ferrocenyl]methyl}dimethylammonium cation has an approximate synclinal eclipsed conformation and is tilted by 3.40 (11)°.【 授权许可】
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