期刊论文详细信息
Acta Crystallographica Section E: Crystallographic Communications | |
Crystal structure of a methimazole-based ionic liquid | |
Zayas, M.S.1  Gaitor, J.C.1  Mirjafari, A.1  Reilly, J.T.1  Myrthil, D.J.1  Hendrich, J.M.2  Sykora, R.E.2  White, F.2  O'Brien, R.A.2  | |
[1] Department of Chemistry and Physics, Florida Gulf Coast University, Fort Myers, FL 33965, USA;University of South Alabama, Department of Chemistry, Mobile, AL 36688, USA | |
关键词: CRYSTAL STRUCTURE; IONIC LIQUIDS; METHIMAZOLE; S-ALLYLATION; NITROGEN HETEROCYCLE; | |
DOI : 10.1107/S2056989015022136 | |
学科分类:数学(综合) | |
来源: International Union of Crystallography | |
【 摘 要 】
The structure of 1-methyl-2-(prop-2-en-1-ylsulfanyl)-1H-imidazol-3-ium bromide, C7H11N2S+·Br−, has monoclinic (P21/c) symmetry. In the crystal, the components are linked by N—H⋯Br and C—H⋯Br hydrogen bonds. The crystal structure of the title compound undeniably proves that methimazole reacts through the thione tautomer, rather than the thiol tautomer in this system.
【 授权许可】
CC BY
【 预 览 】
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