Crystal structure of [(2S,3R)-3-hy­droxy-3-phenyl­butan-2-yl]pyrrolidinium chloride

Acta Crystallographica Section E: Crystallographic Communications

Kandhaswamy, A.¹  Meena, K.S.¹  Deepa, S.²  Murugavel, S.³ 

[1] Department of Chemistry, Queen Mary's College, Chennai 600 004, Tamilnadu, India;Department of Physics, Government College of Engineering, Salem 636 011, India;Department of Physics, Thanthai Periyar Government Institute of Technology, Vellore 632 002, India

关键词: CRYSTAL STRUCTURE;    SALT;    PYRROLIDINIUM CHLORIDE;    IONIC LIQUIDS;    HYDROGEN BONDING;   

DOI  :  10.1107/S2056989015016916

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

In the title mol­ecular salt, C14H22NO+·Cl−, the pyrrolidinium ring adopts a twisted conformation about one of the N—C bonds. It is oriented at a dihedral angle of 42.0 (1)° with respect to the benzene ring. The torsion angle for the central N—C—C—Car (ar = aromatic) linkage is 163.74 (15)°. In the crystal, the components are linked via N—H⋯Cl and O—H⋯Cl hydrogen bonds, forming zigzig chains along the b-axis direction. These chains are connected along the c axis by very weak C—H⋯π inter­actions, forming a two-dimensional supra­molecular network.

【 授权许可】

CC BY