Crystal structure of [UO2(NH3)5]NO3·NH3

Acta Crystallographica Section E: Crystallographic Communications

Woidy, P.¹  Kraus, F.² 

[1] Anorganische Chemie, Fluorchemie, Philipps-Universität Marburg, Hans-Meerwein-Strasse 4, 35032 Marburg, Germany

关键词: CRYSTAL STRUCTURE;    URANIUM(V);    NITRATE;    AMMONIA;    HYDROGEN BONDING;   

DOI  :  10.1107/S2056989016016480

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

Penta­ammine dioxide uranium(V) nitrate ammonia (1/1), [UO2(NH3)5]NO3·NH3, was obtained in the form of yellow crystals from the reaction of caesium uranyl nitrate, Cs[UO2(NO3)3], and uranium tetra­fluoride, UF4, in dry liquid ammonia. The [UO2]+ cation is coordinated by five ammine ligands. The resulting [UO2(NH3)5] coordination polyhedron is best described as a penta­gonal bipyramid with the O atoms forming the apices. In the crystal, numerous N—H⋯N and N—H⋯O hydrogen bonds are present between the cation, anion and solvent mol­ecules, leading to a three-dimensional network.

【 授权许可】

CC BY