Crystal structures of two deca­vanadates(V) with penta­aqua­manganese(II) pendant groups: (NMe4)2[V10O28{Mn(H2O)5}2]·5H2O and [NH3C(CH2OH)3]2[V10O28{Mn(H2O)5}2]·2H2O

Acta Crystallographica Section E: Crystallographic Communications

diger, A.L.¹  Franco, M.P.²  Hughes, D.L.²  Soares, J.F.⁴  Rü⁵  Nunes, G.G.⁶ 

[1] , Centro PolitéDepartamento de QuíSchool of Chemistry, University of East Anglia, Norwich NR4 7TJ, England;cnico, Jardim das Amémica, Universidade Federal do Paranáricas, 81530-900 Curitiba, PR, Brazil

关键词: CRYSTAL STRUCTURE;    DECAVANADATE;    HETEROPOLYANION;    MANGANESE(II);    ORGANIC CATIONS;   

DOI  :  10.1107/S2056989014028230

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

Two heterometallic deca­vanadate(V) compounds, bis­(tetra­methyl­ammonium) deca­aquadi-μ4-oxido-tetra-μ3-oxido-hexa­deca-μ2-oxido-hexa­oxidodimang­anese(II)­deca­vanadate(V) penta­hydrate, (Me4N)2[V10O28{Mn(H2O)5}2]·5H2O, A, and bis­{[tris­(hy­droxy­meth­yl)meth­yl]ammonium} deca­aquadi-μ4-oxido-tetra-μ3-oxido-hexa­deca-μ2-oxido-hexa­oxidodimanganese(II)deca­vanadate(V) dihydrate, [NH3C(CH2OH)3]2[V10O28{Mn(H2O)5}2]·2H2O, B, have been synthesized under mild reaction conditions in an aqueous medium. Both polyanions present two [Mn(OH2)5]2+ complex units bound to the deca­vanadate cluster through oxide bridges. In A, the deca­vanadate unit has 2/m symmetry, whereas in B it has twofold symmetry. Apart from this, the main differences between A and B rest on the organic cations, tetra­methyl­ammonium and [tris­(hy­droxy­meth­yl)meth­yl]ammonium, respectively, and on the number and arrangement of the water mol­ecules of crystallization. In both compounds, the H atoms from the coordinating water mol­ecules participate in extensive three-dimensional hydrogen-bonding networks, which link the cluster units both directly and through solvent mol­ecules and, in B, through the `tris­' cation hydroxyl groups. The cation in B also participates in N—H⋯O hydrogen bonds. A number of C—H⋯O inter­actions are also observed in both structures.

【 授权许可】

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