Crystal structure of hexa­kis­(dimethyl sulfoxide-κO)manganese(II) diiodide

Acta Crystallographica Section E: Crystallographic Communications

Weil, M.¹  Glatz, M.²  Kirchner, K.²  Schroffenegger, M.² 

[1] Institute for Chemical Technologies and Analytics, Division of Structural Chemistry, Vienna University of Technology, Getreidemarkt 9/164-SC, A-1060 Vienna, Austria;Institute of Applied Synthetic Chemistry, Vienna University of Technology, Getreidemarkt 9/163, A-1060 Vienna, Austria

关键词: CRYSTAL STRUCTURE;    DIMETHYL SULFOXIDE;    MANGANESE(II);    OCTAHEDRAL COORDINATION;   

DOI  :  10.1107/S2056989016008896

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The asymmetric unit of the title salt, [Mn(C2H6OS)6]I2, consists of one MnII ion, six O-bound dimethyl sulfoxide (DMSO) ligands and two I− counter-anions. The isolated complex cations have an octa­hedral configuration and are grouped in hexa­gonally arranged rows extending parallel to [100]. The two I− anions are located between the rows and are linked to the cations through two weak C—H⋯I inter­actions.

【 授权许可】

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