Crystal structure of bis­(4-acetyl­pyridine-κN)bis­(ethanol-κO)bis­(thio­cyanato-κN)manganese(II)

Acta Crystallographica Section E: Crystallographic Communications

Werner, J.¹  ther, C.¹  Jess, I.²  Nä³ 

[1] Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth-Strasse 2, 24118 Kiel, Germany

关键词: CRYSTAL STRUCTURE;    MANGANESE(II);    OCTAHEDRAL COORDINATION;    HYDROGEN BONDING;   

DOI  :  10.1107/S2056989015004533

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

In the crystal structure of the title compound, [Mn(NCS)2(C7H7NO)2(C2H5OH)2], the MnII atom is coordin­ated by two N-bonded thio­cyanate anions, two 4-acetyl­pyridine ligands, and two ethanol mol­ecules within a slightly distorted octa­hedron. The asymmetric unit consits of one manganese cation, located on a centre of inversion, one thio­cyanate anion, one 4-acetyl­pyridine ligand and one ethanol mol­ecule in general positions. The discrete complexes are connected by inter­molecular O—H⋯O hydrogen bonds between the alcohol OH group and the carbonyl O atom into chains parallel to [011].

【 授权许可】

CC BY