Acta Crystallographica Section E: Crystallographic Communications | |
Crystal structure of bis(4-acetylpyridine-κN)bis(ethanol-κO)bis(thiocyanato-κN)manganese(II) | |
Werner, J.1  ther, C.1  Jess, I.2  Nä3  | |
[1] Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth-Strasse 2, 24118 Kiel, Germany | |
关键词: CRYSTAL STRUCTURE; MANGANESE(II); OCTAHEDRAL COORDINATION; HYDROGEN BONDING; | |
DOI : 10.1107/S2056989015004533 | |
学科分类:数学(综合) | |
来源: International Union of Crystallography | |
【 摘 要 】
In the crystal structure of the title compound, [Mn(NCS)2(C7H7NO)2(C2H5OH)2], the MnII atom is coordinated by two N-bonded thiocyanate anions, two 4-acetylpyridine ligands, and two ethanol molecules within a slightly distorted octahedron. The asymmetric unit consits of one manganese cation, located on a centre of inversion, one thiocyanate anion, one 4-acetylpyridine ligand and one ethanol molecule in general positions. The discrete complexes are connected by intermolecular O—H⋯O hydrogen bonds between the alcohol OH group and the carbonyl O atom into chains parallel to [011].
【 授权许可】
CC BY
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