Crystal structure of 4-methyl­benzyl N′-[(thio­phen-2-yl)methyl­idene]hydrazinecarbodi­thio­ate

Acta Crystallographica Section E: Crystallographic Communications

Tahir, M.I.M.¹  Ravoof, T.B.S.A.¹  Ramli, S. binti¹  Tiekink, E.R.T.² 

[1] Department of Chemistry, Universiti Putra Malaysia, 43400 Serdang, Malaysia;Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia

关键词: CRYSTAL STRUCTURE;    HYDROGEN BONDING;    DITHIOCARBAZATE;    C-H...[PI] INTERACTIONS;   

DOI  :  10.1107/S205698901501107X

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

In the title compound, C15H16N2S3 {systematic name: [({[(4-methyl­phen­yl)meth­yl]sulfan­yl}methane­thio­yl)amino][1-(thio­phen-2-yl)ethyl­idene]amine}, the central CN2S2 residue is almost planar (r.m.s. deviation = 0.0061 Å) and forms dihedral angles of 7.39 (10) and 64.91 (5)° with the thienyl and p-tolyl rings, respectively; the dihedral angle between these rings is 57.52 (6)°. The non-thione S atoms are syn, and with respect to the thione S atom, the benzyl group is anti. In the crystal, centrosymmetrically related mol­ecules self-associate via eight-membered {⋯HNCS}2 synthons. The dimeric aggregates stack along the a axis and are are consolidated into a three-dimensional architecture via methyl-C—H⋯π(benzene) and benzene-C—H⋯π(thien­yl) inter­actions.

【 授权许可】

CC BY