Crystal structure of (Z)-4-methylbenzyl 3-[1-(5-methylpyridin-2-yl)ethylidene]dithiocarbazate

Acta Crystallographica Section E: Crystallographic Communications

Tiekink, E.R.T.¹  Tahir, M.I.M.²  Begum, S.Z.²  Ravoof, T.B.S.A.²  Omar, S.A.² 

[1] Centre for Crystalline Materials, Faculty of Science and Technology, Sunway University, 47500 Bandar Sunway, Selangor Darul Ehsan, Malaysia;Department of Chemistry, Universiti Putra Malaysia, 43400 Serdang, Malaysia

关键词: CRYSTAL STRUCTURE;    HYDROGEN BONDING;    DITHIOCARBAZATE;   

DOI  :  10.1107/S205698901502407X

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

In the title di­thio­carbazate compound, C17H19N3S2, the central CN2S2 residue is essentially planar (r.m.s. deviation = 0.0288 Å) and forms dihedral angles of 9.77 (8) and 77.47 (7)° with the substituted-pyridyl and p-tolyl rings, respectively, indicating a highly twisted mol­ecule; the dihedral angle between the rings is 85.56 (8)°. The configuration about the C=N bond is Z, which allows for the formation of an intra­molecular N—H⋯N(pyrid­yl) hydrogen bond. The packing features tolyl-methyl-C—H⋯N(imine), pyridyl-C—H⋯π(tol­yl) and π–π inter­actions [between pyridyl rings with a distance = 3.7946 (13) Å], which generates jagged supra­molecular layers that stack along the b axis with no directional inter­actions between them.

【 授权许可】

CC BY