Crystal structure of bis­(3,5-di­methyl­pyridine-κN)bis­(methanol-κO)bis­(thio­cyanato-κN)cobalt(II)

Acta Crystallographica Section E: Crystallographic Communications

ther, C.¹  Suckert, S.¹  Jess, I.²  Nä³ 

[1] Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth Strasse 2, D-24118 Kiel, Germany

关键词: CRYSTAL STRUCTURE;    COBALT(II) THIOCYANATE COMPLEX;    3,5-DIMETHYLPYRIDINE LIGAND;    HYDROGEN BONDING;   

DOI  :  10.1107/S2056989016018326

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The asymmetric unit of the title complex, [Co(NCS)2(C7H9N)2(CH3OH)2], comprises of one CoII cation located on a centre of inversion, one thio­cyanate ligand, one methanol ligand and one 3,5-di­methyl­pyridine ligand. The CoII cation is octa­hedrally coordinated by two terminal N-bonding thio­cyanate anions, two methanol mol­ecules and two 3,5-di­methyl­pyridine ligands into a discrete complex. The complex mol­ecules are linked by inter­molecular O—H⋯S hydrogen bonding into chains that elongate in the direction parallel to the b axis.

【 授权许可】

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