Crystal structure of bis­{1-[(E)-(2-meth­oxy­phen­yl)diazen­yl]naphthalen-2-olato-κ3O,N2,O′}copper(II) containing an unknown solvate

Acta Crystallographica Section E: Crystallographic Communications

Hamdouni, N.²  Bouaoud, S.E.³  Chetioui, S.⁵  Rouag, D.-A.⁶  Merazig, H.⁷ 

[1] Constantine 1, Constantine 25000, Algeria;de Recherche de Chimie de l'Environnement et Molédes Sciences Exactes, DéLaboratoire de Cristallographie, DéUnitéculaire Structurale (CHEMS), Facultépartement de Chimie, Universitépartement de Physique, Université

关键词: CRYSTAL STRUCTURE;    NAPHTHALEN-2-OLATE;    COPPER(II) COMPLEX;    OCTAHEDRAL COORDINATION;    AZO COMPOUNDS;   

DOI  :  10.1107/S2056989015019817

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The title complex, [Cu(C17H13N2O2)2], crystallizes with two independent mol­ecules in the asymmetric unit. Each CuII atom has a distorted ocahedral coordination environment defined by two N atoms and four O atoms from two tridentate 1-[(E)-(2-meth­oxy­phen­yl)diazen­yl]naphthalen-2-olate ligands. In the crystal, the two mol­ecules are linked via weak C—H⋯O hydrogen bonds which in turn stack parallel to [010]. A region of disordered electron density, most probably disordered methanol solvent molecules, was corrected for using the SQUEEZE routine in PLATON [Spek (2015). Acta Cryst. C71, 9–18]. Their formula mass and unit-cell characteristics were not taken into account during refinement.

【 授权许可】

CC BY