Crystal structure of 4-[(E)-(2-carbamo­thio­ylhydrazinyl­idene)meth­yl]benzoic acid

Acta Crystallographica Section E: Crystallographic Communications

Choudhary, M.A.¹  Tahir, M.N.²  Anwar-ul-Haq, M.² 

[1] Department of Chemistry, Mirpur University of Science and Technology (MUST), Mirpur, Azad Jammu and Kashmir, Pakistan;Department of Physics, University of Sargodha, Sargodha, Punjab, Pakistan

关键词: CRYSTAL STRUCTURE;    HYDRAZINECARBOTHIOAMIDE;    HYDROGEN BONDING;   

DOI  :  10.1107/S2056989015017594

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The title compound, C9H9N3O2S, is close to planar with an r.m.s. deviation of 0.032 Å. An intra­molecular N—H⋯N hydrogen bond closes an S(5) ring. In the crystal, mol­ecules are connected into inversion dimers of the R22(8) type by pairs of O—H⋯O inter­actions. The dimers are further connected by pairs of N—H⋯S inter­actions, which also complete R22(8) ring motifs. The chains of dimers are cross-linked by N—H⋯O bonds and hence R42(28) rings are completed. Taken together, these inter­actions lead to infinite sheets propagating in the (122) plane.

【 授权许可】

CC BY