Crystal structure of 3-[(E)-(2-hy­droxy-3-meth­oxy­benzyl­idene)amino]-1-methyl-1-phenyl­thio­urea

Acta Crystallographica Section E: Crystallographic Communications

Rahman, A.A.¹  Sreekanth, A.¹  Muralisankar, M.¹  Gangadharan, R.²  Sethusankar, K.³ 

[1] Department of Chemistry, National Institute of Technology, Tiruchirappalli 620 015, India;Department of Physics, Ethiraj College for Women (Autonomous), Chennai 600 008, India;Department of Physics, RKM Vivekananda College (Autonomous), Chennai 600 004, India

关键词: CRYSTAL STRUCTURE;    HYDRAZINECARBOTHIOAMIDE;    THIOUREA DERIVATIVES;    [ALPHA]-N-HETEROCYCLIC;    HYDROGEN BONDING;   

DOI  :  10.1107/S2056989016005326

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

In the asymmetric unit of the title compound, C16H17N3O2S, there are two independent mol­ecules (A and B), which show an E conformation with respect to the C=N bond. An intra­molecular O—H⋯N hydrogen bond with an S(6) motif stabilizes the mol­ecular structure. The terminal phenyl and benzene rings are almost orthogonal to each other, the dihedral angle being 87.47 (13)° for mol­ecule A and 89.86 (17)° for mol­ecule B. In the crystal, weak bifurcated N—H⋯(O,O) hydrogen bonds link the two independent mol­ecules, forming a supra­molecular chain with a C21(14)[R21(5)] motif along the b axis. A weak C—H⋯O inter­action is also observed in the chain.

【 授权许可】

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