Crystal structure of 4-[(E)-(4-nitro­benzyl­idene)amino]­phenol

Acta Crystallographica Section E: Crystallographic Communications

Atioğ¹  kgü²  ngö²  r, O.³  yü⁴  Akkurt, M.⁵  Bü⁶  lu, Z.⁷  Ebrahimi, E.⁸  Jarrahpour, A.⁹ 

[1] İDepartment of Chemistry, College of Sciences, Shiraz University, 71454 Shiraz, Iran;Department of Physics, Faculty of Arts and Sciences, Ondokuz MayıDepartment of Physics, Faculty of Sciences, Erciyes University, 38039 Kayseri, Turkey;a, Üehir, Turkey;lke Education and Health Foundation, Cappadocia Vocational College, The Medical Imaging Techniques Program, 50420 Mustafapaşp, Nevşrgüs University, 55139 Samsun, Turkey

关键词: CRYSTAL STRUCTURE;    WHOLE-MOLECULE DISORDER;    NITROAROMATIC COMPOUNDS;    HYDROGEN BONDING;    C-H...[PI] INTERACTIONS;    [PI]-[PI] STACKING INTERACTIONS;   

DOI  :  10.1107/S2056989015000511

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The asymmetric unit of the title compound, C13H10N2O3, contains four independent mol­ecules (I, II, III and IV). Mol­ecule IV shows whole-mol­ecule disorder over two sets of adjacent sites in a 0.669 (10):0.331 (10) ratio. The dihedral angles between the aromatic rings are 32.30 (13)° in mol­ecule I, 2.24 (14)° in II, 41.61 (13)° in III, 5.0 (5)° in IV (major component) and 10.2 (3)° in IV (minor component). In the crystal, mol­ecules are linked into layers lying parallel to (024) by C—H⋯O and O—H⋯O inter­actions. The layers inter­act by C—H⋯π and weak aromatic π–π stacking inter­actions [centroid–centroid distances = 3.8476 (16), 3.725 (3) and 3.733 (5) Å].

【 授权许可】

CC BY