Synthesis and crystal structure of bis­(μ-2-methyl­benzene­thiol­ato-κ2S:S)bis­[meth­yl(2-methyl­benzene­thiol­ato-κS)indium(III)]

Acta Crystallographica Section E: Crystallographic Communications

Briand, G.G.¹  MacNeil, G.¹  Dickie, C.M.¹  Decken, A.² 

[1]Department of Chemistry and Biochemistry, Mount Allison University, 63C York Street, Sackville, NB, E4L 1G8, Canada

[2]Department of Chemistry, University of New Brunswick, Fredericton, NB, E3B 5A3, Canada

关键词: CRYSTAL STRUCTURE;    INDIUM;    THIOLATE;    DINUCLEAR;    COORDINATION POLYMER;   

DOI  :  10.1107/S2056989017003498

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The dinuclear title compound, [In2(CH3)2(C7H7S)4] or [Me(2-MeC6H4S)In-μ-(2-MeC6H4S)2InMe(2-MeC6H4S)], was prepared from the 1:2 reaction of Me3In and 2-MeC6H4SH in toluene. Its crystal structure exhibits a four-membered In2S2 ring core via bridging (2-MeC6H4S) groups. The dimeric units are further associated into a one-dimensional polymeric structure extending parallel to the a axis via inter­molecular In⋯S contacts. The In atoms are then in distorted trigonal–bipyramidal CS4 bonding environments.

【 授权许可】

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