Crystal structure of dimethyl-1κ2C-bis(μ-4-methylphenolato-1:2κ2O:O)(N,N,N′,N′-tetramethylethylenediamine-2κ2N,N′)indium(III)lithium(I)

Acta Crystallographica Section E: Crystallographic Communications

Hoey, M.R.¹  Briand, G.G.¹  Decken, A.² 

[1] Department of Chemistry and Biochemistry, Mount Allison University, Sackville, New Brunswick, E4L 1G8, Canada;Department of Chemistry, University of New Brunswick, Fredericton, New Brunswick, E3B 5A3, Canada

关键词: CRYSTAL STRUCTURE;    BIMETALLIC;    INDIUM;    LITHIUM;    PHENOLATE;    SPIROCYCLIC;   

DOI  :  10.1107/S2056989015023476

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The mixed bimetallic title compound, [InLi(CH3)2(C7H7O)2(C6H16N2)] or [(tmeda)Li-μ-(4-MeC6H4O)2InMe2] (tmeda is N,N,N′,N′-tetra­methyl­ethylenedi­amine), exhibits a four-membered LiO2In ring core via bridging 4-methyl­phenolate groups. The Li and In atoms are in distorted tetra­hedral N2O2 and C2O2 bonding environments, respectively. The Li atom is further chelated by a tmeda group, yielding a spiro­cyclic structure.

【 授权许可】

CC BY