Crystal structure of bis­[μ-1,2-bis­(di­phenyl­phosphan­yl)ethane-κ2P:P′]bis[(N,N′-di­ethyl­thio­urea-κS)iodidocopper(I)]

Acta Crystallographica Section E: Crystallographic Communications

Khongsichan, L.¹  n, A.¹  Pakawatchai, C.¹  Nimthong-Roldá² 

[1] Department of Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla 90112, Thailand;Department of Chemistry, Youngstown State University, 1 University Plaza, 44555 Youngstown, OH, USA

关键词: CRYSTAL STRUCTURE;    COPPER(I) COMPLEX;    N,N'-DIETHYLTHIOUREA;    N-H...I HYDROGEN BONDING;   

DOI  :  10.1107/S2056989015014176

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The binuclear title complex, [Cu2I2(C26H24P2)2(C5H12N2S)2], lies about an inversion centre. The CuI atom displays a distorted tetra­hedral coordination geometry defined by one S atom of an N,N′-di­ethyl­thio­urea ligand, two P atoms derived from two bridging 1,2-bis­(di­phenyl­phosphan­yl)ethane (dppe) ligands and one iodide ion. The dppe ligand bridges two symmetry-related CuI ions, forming a 10-membered Cu2P4C4 ring. An intra­molecular N—H⋯I hydrogen bond is noted. In the crystal, N—H⋯I hydrogen bonds link complex mol­ecules into layers parallel to (-101).

【 授权许可】

CC BY