Crystal structure of (aceto­nitrile-κN)iodido­(2-(naphthalen-1-yl)-6-{1-[(2,4,6-tri­methyl­phen­yl)imino]ethyl}­pyridine-κ2N,N′)copper(I)

Acta Crystallographica Section E: Crystallographic Communications

Al-Najjar, N.¹  Solan, G.A.²  Singh, K.² 

[1] Department of Chemistry, College of Science for Women, University of Baghdad, Iraq;Department of Chemistry, University of Leicester, University Road, Leicester LE1 7RH, England

关键词: CRYSTAL STRUCTURE;    COPPER(I) COMPLEX;    2-IMINO-6-(NAPHTHALEN-1-YL)PYRIDINE;    SCHIFF BASE;    IODIDE;    BIDENTATE LIGAND;   

DOI  :  10.1107/S2056989016018685

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

In the mononuclear title complex, [CuI(C2H3N)(C26H24N2)], the CuI ion has a distorted tetra­hedral coordination environment, defined by two N atoms of the chelating 2-(naphthalen-1-yl)-6-[(2,4,6-tri­methyl­phen­yl)imino]­pyridine ligand, one N atom of an aceto­nitrile ligand and one iodide ligand. Within the complex, there are weak intra­molecular C—H⋯N hydrogen bonds, while weak inter­molecular C—H⋯I inter­actions between complex mol­ecules, help to facilitate a three-dimensional network.

【 授权许可】

CC BY