Crystal structure of 3-benzyl-1-[(cyclo­hexyl­idene)amino]­thio­urea

Acta Crystallographica Section E: Crystallographic Communications

Mague, J.T.¹  Akkurt, M.²  Albayati, M.R.²  Hassan, A.A.³  Abdel-Aziz, A.T.⁴  Mohamed, S.K.⁵ 

[1]Engineering, School of Healthcare Science, Manchester Metropolitan University, Manchester M1 5GD, England

[2]Chemistry Department, Faculty of Science, Minia University, 61519 El-Minia, Egypt

[3]Department of Chemistry, Tulane University, New Orleans, LA 70118, USA

[4]Department of Physics, Faculty of Sciences, Erciyes University, 38039 Kayseri, Turkey

[5]Faculty of Science &

关键词: CRYSTAL STRUCTURE;    THIOUREAS;    CHELATING AGENTS;    HYDROGEN BONDING;   

DOI  :  10.1107/S205698901502112X

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The conformation of the title compound, C14H19N3S, is partially determined by an intra­molecular N—H⋯N hydro­gen-bond inter­action, although the N—H⋯N angle of 108° is quite small. The cyclo­hexyl­idene ring has a chair conformation and its mean plane is inclined to the benzene ring by 46.30 (8)°. In the crystal, mol­ecules are linked by pairs of N—H⋯S hydrogen bonds, forming inversion dimers, with an R22(8) ring motif. The dimers are reinforced by pairs of C—H⋯S hydrogen bonds, and are linked by further weak C—H⋯S hydrogen bonds, forming chains propagating along [100].

【 授权许可】

CC BY