Crystal structure of (±)-1-({[4-(all­yloxy)phen­yl]sulfan­yl}meth­yl)-2-(di­phenyl­thio­phosphor­yl)ferrocene

Acta Crystallographica Section E: Crystallographic Communications

Sarda, S.³  Manoury, E.⁴  Daran, J.-C.⁵  Michelot, A.⁷  Deydier, E.⁹ 

[1] Bureau 2-r1-5, 4 AlléPaul Sabatier, ENSIACET –de Toulouse, UPS, INPT, F-31077 Toulouse Cedex 4, France;CIRIMAT, éCNRS, LCC (Laboratoire de Chimie de Coordination), IUT, DéLaboratoire de Chimie de Coordination, 205 route de Narbonne, 31077 Toulouse, Cedex 04, France;Universitée Emile Monso BP 44362, 31432 Toulouse Cedex 4, France;partement de Chimie, avenue Georges Pompidou, BP258, 81104 Castres, France;quipe PPB, Université

关键词: CRYSTAL STRUCTURE;    FERROCENYL LIGANDS;    PLANAR CHIRALITY;    ASYMMETRIC CATALYSIS;   

DOI  :  10.1107/S2056989015013560

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The title compound, [Fe(C5H5)(C27H24OPS2)], is built up from a ferrocene moiety substituted in the 1- and 2-positions by {[4-(all­yloxy)phen­yl]sulfan­yl}methyl and di­phenyl­thio­phosphoryl groups, respectively. The two S atoms lie on opposite sides of the cyclo­penta­dienyl ring plane to which they are attached. In the crystal, C—H⋯S hydrogen bonds link the mol­ecules into a ribbon running parallel to the (-110) plane. C—H⋯π inter­actions link the ribbons to form a three-dimensional network.

【 授权许可】

CC BY