Crystal structure of (Z)-3-allyl-5-(3-bromo­benzyl­idene)-2-sulfanyl­idene-1,3-thia­zolidin-4-one

Acta Crystallographica Section E: Crystallographic Communications

Rakib, E.M.²  Forsal, I.³  El Ammari, L.⁵  El Ajlaoui, R.⁵  Saadi, M.⁸ 

[1] Mohammed V de Rabat, Avenue Ibn Battouta, BP. 1014, Rabat, Morocco;Sultan Moulay Slimane, Facultédes Sciences et Techniques, Bédes Sciences, UniversitéLaboratoire de Chimie Organique et Analytique, UniversitéLaboratoire de Chimie du Solide Appliquée, Faculténi-Mellal, BP 523, Morocco

关键词: CRYSTAL STRUCTURE;    RHODANINE;    HYDROGEN BONDING;   

DOI  :  10.1107/S2056989015022884

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

In the title compound, C13H10BrNOS2, the rhodanine (systematic name: 2-sulfanyl­idene-1,3-thia­zolidin-4-one) and the 3-bromo­benzyl­idene ring systems are inclined slightly, forming a dihedral angle of 5.86 (12)°. The rhodanine moiety is linked to an allyl group at the N atom and to the 3-bromo­benzyl­idene ring system. The allyl group, C=C—C, is nearly perpendicular to the mean plane through the rhodanine ring, maling a dihedral angle of 87.2 (5)°. In the crystal, mol­ecules are linked by pairs of C—H⋯O hydrogen bonds, forming inversion dimers with an R22(10) ring motif.

【 授权许可】

CC BY