Crystal structure of 4-meth­oxy-N-(piperidine-1-carbono­thio­yl)benzamide

Acta Crystallographica Section E: Crystallographic Communications

Ahmad, M.¹  Kassim, M.B.²  Hasbullah, S.A.³  Suhud, K.⁴  Heng, L.Y.⁴ 

[1] Natural Science Faculty, Universitas Syiah Kuala, Banda Aceh, 23111, Indonesia;Chemical Technology Program, Faculty of Science Technology, Universiti Sains Islam Malaysia, Bandar Baru Nilai, 71800 Nilai, Negeri Sembilan;Department of Chemistry, Mathematic &School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Selangor, Malaysia

关键词: CRYSTAL STRUCTURE;    BENZOYLTHIOUREA;    PIPERIDINE;    PYRROLIDINE;    BENZAMIDE;    ANTI-CANCER;    HYDROGEN BONDING;    C-H...[PI] INTERACTIONS;    OFFSET [PI]-[PI] INTERACTIONS;   

DOI  :  10.1107/S2056989017013317

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

In the title compound, C14H18N2O2S, the piperidine ring has a chair conformation. Its mean plane is twisted with respect to the 4-meth­oxy­benzoyl ring, with a dihedral angle of 63.0 (3)°. The central N—C(=S)—N(H)—C(=O) bridge is twisted with an N—C—N—C torsion angle of 74.8 (6)°. In the crystal, mol­ecules are linked by N—H⋯O and C—H⋯O hydrogen bonds, forming chains along the c-axis direction. Adjacent chains are linked by C—H⋯π inter­actions, forming layers parallel to the ac plane. The layers are linked by offset π–π inter­actions [inter­centroid distance = 3.927 (3) Å], forming a supra­molecular three-dimensional structure.

【 授权许可】

CC BY