Ruthenium-catalyzed intermolecular [2+2+2] alkyne cyclotrimerization in aqueous media under microwave irradiation

Green Chemistry Letters and Reviews

Victorio Cadierno¹ 

关键词: ruthenium;    alkynes;    cyclotrimerization;    microwave chemistry;    water;   

DOI  :  10.1080/17518253.2010.500623

学科分类：化学（综合）

来源: Taylor & Francis

【 摘 要 】

The ability of the bis(allyl)-ruthenium(IV) complex [{RuCl(µ-Cl)(η3: η3-C10H16)}2] (C10H16=2,7-dimethylocta-2,6-diene-1,8-diyl) to promote intermolecular [2+2+2] alkyne cyclotrimerization reactions in aqueous media under microwave (MW) irradiation has been evaluated. Advantages and disadvantages of using MW vs. conventional thermal heating are discussed.

【 授权许可】

Unknown