Crystal structure of chlorido­[trans-1-(di­phenyl­phosphane­thioyl-κS)-2-(di­phenyl­phosphano­yl)ethene]gold(I) di­chloro­methane hemisolvate

Acta Crystallographica Section E: Crystallographic Communications

Taouss, C.¹  Jones, P.G.² 

[1] Institut für Anorganische und Analytische Chemie, Technische Universität Braunschweig, Postfach 3329, D-38023 Braunschweig, Germany

关键词: CRYSTAL STRUCTURE;    GOLD;    PHOSPHINE;    CHALCOGENIDE;   

DOI  :  10.1107/S2056989016009816

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The title compound, [AuCl(C26H22OP2S)]·0.5CH2Cl2, crystallizes with a trans-O—P⋯P—S geometry of the groups either side of the C=C double bond, which prevents any intra­molecular contact between the Au and O atoms. The AuI atom exhibits a nearly linear coordination [Cl—Au—S = 177.55 (4)°]. The mol­ecules associate to form broad ribbons parallel to the c axis via two C—H⋯O, one C—H⋯Cl(Au) and one Au⋯Cl inter­action.

【 授权许可】

CC BY