Synthesis and crystal structure of tri­carbonyl­chlorido­{1-[(pyridin-2-yl­methyl­idene)amino]­adamantane}rhenium(I)

Acta Crystallographica Section E: Crystallographic Communications

Jimenez, J.¹  Chakraborty, I.¹  Mascharak, P.¹ 

[1] Department of Chemistry, University of California Santa Cruz, CA 95064, USA

关键词: CRYSTAL STRUCTURE;    RHENIUM COMPLEX;    FAC-RE(CO)3;    LIPOPHILICITY;    ADAMANTANE MOTIF;   

DOI  :  10.1107/S205698901601255X

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The title compound, [ReCl(pyAm)(CO)3], where pyAm is 1-[(pyridin-2-yl­methyl­idene)amino]­adamantane (C16H20N2), was synthesized from the reaction of [ReCl(CO)5] and pyAm in an equimolar ratio. The ReI atom resides in an octa­hedral C3ClN2 coordination sphere. The Re—C bond trans to the chloride ligand is noticeably longer compared to the other two Re—C distances. Weak C—H⋯Cl hydrogen-bonding inter­actions consoldiate the packing of the mol­ecules. In this design, the pyAm ligand was employed due to its well-known pharmacokinetic properties.

【 授权许可】

CC BY