Crystal structures of fac-tri­carbonyl­chlorido­(6,6′-dihy­droxy-2,2′-bi­pyridine)­rhenium(I) tetra­hydro­furan monosolvate and fac-bromido­tricarbon­yl(6,6′-dihy­droxy-2,2′-bi­pyridine)­manganese(I) tetra­hydro­furan monosolvate

Acta Crystallographica Section E: Crystallographic Communications

Lense, S.¹  Wildish, A.¹  Jeffery, B.¹  Kassel, S.W.²  Piro, N.A.² 

[1] University of Wisconsin Oshkosh, Department of Chemistry, 800 Algoma Blvd., Oshkosh, WI 54902, USA;Villanova University, Department of Chemistry, 800 E. Lancaster Avenue, Villanova, PA 19085, USA

关键词: CRYSTAL STRUCTURE;    6;    6'-DIHYDROXY-2;    2'-BIPYRIDINE LIGAND;    RHENIUM COMPLEX;    MANGANESE COMPLEX;    HYDROGEN BONDING;    SELECTIVE CATALYSTS FOR CO2 REDUCTION;   

DOI  :  10.1107/S2056989016011841

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The structures of two facially coordinated Group VII metal complexes, fac-[ReCl(C10H8N2O2)(CO)3]·C4H8O (I·THF) and fac-[MnBr(C10H8N2O2)(CO)3]·C4H8O (II·THF), are reported. In both complexes, the metal ion is coordinated by three carbonyl ligands, a halide ligand, and a 6,6′-dihy­droxy-2,2′-bi­pyridine ligand in a distorted octa­hedral geometry. Both complexes co-crystallize with a non-coordinating tetra­hydro­furan (THF) solvent mol­ecule and exhibit inter­molecular but not intra­molecular hydrogen bonding. In both crystal structures, chains of complexes are formed due to inter­molecular hydrogen bonding between a hy­droxy group from the 6,6′-dihy­droxy-2,2′-bi­pyridine ligand and the halide ligand from a neighboring complex. The THF mol­ecule is hydrogen bonded to the remaining hy­droxy group.

【 授权许可】

CC BY