Acta Crystallographica Section E: Crystallographic Communications | |
Crystal structures of fac-tricarbonylchlorido(6,6′-dihydroxy-2,2′-bipyridine)rhenium(I) tetrahydrofuran monosolvate and fac-bromidotricarbonyl(6,6′-dihydroxy-2,2′-bipyridine)manganese(I) tetrahydrofuran monosolvate | |
Lense, S.1  Wildish, A.1  Jeffery, B.1  Kassel, S.W.2  Piro, N.A.2  | |
[1] University of Wisconsin Oshkosh, Department of Chemistry, 800 Algoma Blvd., Oshkosh, WI 54902, USA;Villanova University, Department of Chemistry, 800 E. Lancaster Avenue, Villanova, PA 19085, USA | |
关键词: CRYSTAL STRUCTURE; 6; 6'-DIHYDROXY-2; 2'-BIPYRIDINE LIGAND; RHENIUM COMPLEX; MANGANESE COMPLEX; HYDROGEN BONDING; SELECTIVE CATALYSTS FOR CO2 REDUCTION; | |
DOI : 10.1107/S2056989016011841 | |
学科分类:数学(综合) | |
来源: International Union of Crystallography | |
【 摘 要 】
The structures of two facially coordinated Group VII metal complexes, fac-[ReCl(C10H8N2O2)(CO)3]·C4H8O (I·THF) and fac-[MnBr(C10H8N2O2)(CO)3]·C4H8O (II·THF), are reported. In both complexes, the metal ion is coordinated by three carbonyl ligands, a halide ligand, and a 6,6′-dihydroxy-2,2′-bipyridine ligand in a distorted octahedral geometry. Both complexes co-crystallize with a non-coordinating tetrahydrofuran (THF) solvent molecule and exhibit intermolecular but not intramolecular hydrogen bonding. In both crystal structures, chains of complexes are formed due to intermolecular hydrogen bonding between a hydroxy group from the 6,6′-dihydroxy-2,2′-bipyridine ligand and the halide ligand from a neighboring complex. The THF molecule is hydrogen bonded to the remaining hydroxy group.
【 授权许可】
CC BY
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