期刊论文详细信息
Bulletin of Materials Science | |
Catalytic oxidation of cyclohexane to cyclohexanone and cyclohexanol by tert-butyl hydroperoxide over Pt/oxide catalysts | |
关键词: Oxidation; cyclohexane; platinum; TBHP; cyclohexanol; cyclohexanone.; | |
学科分类:材料工程 | |
来源: Indian Academy of Sciences | |
【 摘 要 】
Heterogeneous oxidation of cyclohexane with tertiobutyl hydroperoxide was carried out on Pt/oxide (Al2O3, TiO2 and ZrO2) catalysts in the presence of different solvents (acetic acid and acetonitrile). The catalysts were prepared using Pt(NH3)2(NO2)2 as a precursor and characterized by chemical analysis using the ICP–AES method, XRD, TEM, FTIR and BET surface area determination. The oxidation reaction was carried out at 70°C under atmospheric pressure. The results showed the catalytic performance of Pt/Al2O3 as being very high in terms of turnover frequency.
【 授权许可】
CC BY
【 预 览 】
Files | Size | Format | View |
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