Selective oxidation of olefins catalyzed by polymer-anchored nickel(II) complex in water medium

Bulletin of the Korean chemical society

Anupam Singha Roy¹  Manir Mobarak¹  Sanchita Mondal¹  Paramita Mondal¹  Dildar Hossain¹  Manirul Islam¹ 

关键词: Chloromethylated polystyrene;    Nickel (II) complex;    Olefin oxidation;    Water;    TBHP;   

DOI  :  

学科分类：化学（综合）

来源: Korean Chemical Society

【 摘 要 】

Selective oxidation of olefins has been carried out in water medium with tert-butylhydroperoxide (TBHP, 70% aqueous) as an oxidant using polymer-anchored Ni(II) complex as a catalyst. Several parameters were varied to optimize the reaction conditions. Under the optimized reaction conditions olefins gave selectively allylic oxidation products. The present polymer anchored Ni(II) complex can be recycled five times without any appreciable loss in catalytic activity.

【 授权许可】

Unknown