期刊论文详细信息
Acta Crystallographica Section E: Crystallographic Communications | |
Crystal structure of bis(2-methyl-1H-imidazol-3-ium) μ-oxalato-bis[n-butyltrichloridostannate(IV)] | |
Oliver, A.G.1  Diop, L.2  Diop, M.B.2  | |
[1] Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46557-5670, USA;Laboratoire de Chimie Minérale et Analytique, Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, Senegal | |
关键词: CRYSTAL STRUCTURE; ORGANOTIN(IV) COMPLEX; OXALATE; HYDROGEN BONDS; | |
DOI : 10.1107/S2056989016008434 | |
学科分类:数学(综合) | |
来源: International Union of Crystallography | |
【 摘 要 】
The SnIV atom in the centrosymmetric anion of the title salt, (C4H7N2)2[Sn2(C4H9)2(C2O4)Cl6], is coordinated in a distorted octahedral mode by two O atoms of a bridging oxalate moiety, three Cl atoms and a C atom of an n-butyl group. The latter is disordered over two sets of sites in a 0.66:0.33 occupancy ratio. N—H⋯O and N—H⋯Cl hydrogen bonds involving the 2-methylimidazolium cation and neighbouring anions result in the formation of chains extending parallel to [001].
【 授权许可】
CC BY
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