Crystal structure of poly[μ2-aqua-aqua­(μ2-4-nitro-2,5,6-trioxo-1,2,5,6-tetra­hydro­pyridin-3-olato)hemi-μ4-oxalato-barium(II)]

Acta Crystallographica Section E: Crystallographic Communications

Alabada, R.¹  Sergienko, V.²  Polyakova, I.²  Strashnova, S.³  Kovalchukova, O.³ 

[1] Al Muthanna University, Samawah, Al Mutanna, Iraq;Kurnakov Institute of General and Inorganic Chemistry RAS, 31 Leninskiy Avenue, 119991 Moscow, Russian Federation;Peoples' Friendship University of Russia, 6 Miklukho-Mallaya, 117198 Moscow, Russian Federation

关键词: CRYSTAL STRUCTURE;    TWO-DIMENSIONAL COORDINATION POLYMER;    BARIUM(II) COMPOUND;    OXALATE;   

DOI  :  10.1107/S2056989015006520

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

In the title coordination polymer, [Ba(C5HN2O6)(C2O4)0.5(H2O)2]n, the tenfold coordination of the Ba centre consists of four O atoms from the two 4-nitro-2,5,6-trioxo-1,2,5,6-tetra­hydro­pyridin-3-olate (L) anions, three O atoms of two oxalate anions and three water mol­ecules. The Ba—O bond lengths fall in the range 2.698 (3)–2.978 (3) Å. The L ligand chelates two Ba atoms related by a screw axis, leading to formation of fused five- and six-membered chelate rings. Due to the bridging function of the ligands and water mol­ecules, the complex monomers are connected into polymeric two-dimensional layers parallel to the bc plane. Inter­molecular O—H⋯O hydrogen bonds link these layers into a three-dimensional supra­molecular framework.

【 授权许可】

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