Crystal structure of 1-phenyl­imido-1-{6-[1-(phenyl­imino)­eth­yl]pyridin-2-yl}ethan-1-yl-κ3N,N′,N′′)iron(II)

Acta Crystallographica Section E: Crystallographic Communications

Filatov, A.S.¹  Lau, K.-C.¹  Jordan, R.F.¹ 

[1] Department of Chemistry, The University of Chicago, 5735 South Ellis ave, Chicago, Il 60637, USA

关键词: CRYSTAL STRUCTURE;    BIS(IMINO)PYRIDINE LIGAND;    PYRIDINE-DIIMINE;    REDOX-ACTIVE;    IRON;    RADICAL ANION;   

DOI  :  10.1107/S2056989016015528

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The title iron complex, [Fe(C21H19N3)2], consists of an FeII atom chelated by two tridentate bis­(imino)­pyridine radical anions in a slightly distorted octa­hedral coordination environment. In the solid state, there are two independent half-mol­ecules in the asymmetric unit, and the complete mol­ecular structure is formed by applying twofold rotation symmetry with the twofold rotation axis passing through an Fe atom. In the crystal, the Fe-containing complexes are not involved in any particular direct inter­molecular inter­actions, with the shortest C—HAr contacts between neighboring phenyl groups being ca 3.2 Å.

【 授权许可】

CC BY