期刊论文详细信息
Journal of Environmental Health Science Engineering
Evaluation and comparison of aluminum-coated pumice and zeolite in arsenic removal from water resources
Masoumeh Heidari2  Simin Nasseri1 
[1] Department of Environmental Health Engineering, School of Public Health and Center for Water Quality Research, Institute of Environmental Research, Tehran University of Medical Sciences, Tehran, Iran;Department of Environmental Sciences, Sanandaj Branch, Islamic Azad University, Sanandaj, Iran
关键词: Aluminum-coated zeolite;    Aluminum-coated pumice;    Water resources;    Arsenic adsorption;   
Others  :  821262
DOI  :  10.1186/1735-2746-9-38
 received in 2012-12-05, accepted in 2012-12-05,  发布年份 2012
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【 摘 要 】

In this research the potential of aluminum-coated pumice and zeolite in arsenic, As (V) removal was investigated and compared. Scanning Electron Microscopy (SEM), X-Ray Diffraction (XRD) and X-Ray Flaorescence Spectrometry (XRF) were carried out to determine the properties of the adsorbents. Several parameters including adsorbent dosage] pH, contact time, and initial As(V) concentration were studied. The optimum pH obtained for both adsorbents was pH = 7. As(V) adsorption by both adsorbents followed the Freundlich isotherm (for aluminum-coated pumice and zeolite respectively with R2 > 0.98 and R2 > 0.99). The obtained data from kinetics showed that the pseudo-second order model could better explain As(V) adsorption for both aluminum-coated pumice and zeolite (R2 > 0.98 and R2 > 0.99 respectively). Because of low cost, both adsorbents may be economically used, but aluminum-coated zeolite showed high efficiency of, due to its porosity and surface area. More than 96% of As(V) with initial concentration of 250 μg/L was removed by 10 g/L aluminum-coated zeolite at pH = 7 and in 60 minutes to achieve As(V) concentration of 10 μg/L, while only 71% of As(V) could be removed by aluminum-coated pumice.

【 授权许可】

   
2012 Nasseri and Heidari; licensee BioMed Central Ltd.

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【 参考文献 】
  • [1]Jeong Y, Fan M, Singh S, Chuangd CL, Saha B, Leeuwenb JH: Evaluation of iron oxide and aluminum oxide as potential arsenic(V) adsorbents. Chem. Eng. & Proc 2007, 46:1030-1039.
  • [2]Pokhrel D, Viraraghavan T: Arsenic removal from an aqueous solution by modified A. niger biomass: Batch kinetic and isotherm studies. J Hazard Mater 2007, 6864:1-8.
  • [3]Rahmani AR, Ghaffari HR, Samadi MT: A comparative study on arsenic(III) removal from aqueous solution using nano and micro sized zero-valent iron. Iran J Environ Health Sci Eng 2011, 8(2):175-180.
  • [4]Haque N, Morrison G, Aguilera IC, Torresdey JLG: Iron-modified light expanded clay aggregates for the removal of arsenic(V) from groundwater. Microchem J 2008, 88:7-13.
  • [5]Dutta PK, Pehkonen SO, Sharma VK, Ray AK: Photocatalytic oxidation of arsenic(III): Evidence of hydroxyl radicals. Environ Sci Technol 2005, 39:1827-1834.
  • [6]Pena ME, Korfiatis GP, Patel M, Lippincott L, Meng X: Adsorption of As(V) and As(III) by nanocrystalline titanium dioxide. Water Res 2005, 39:2327-2337.
  • [7]Akbari HR, Rashidi Mehrabadi A, Torabian A: Determination of nanofiltration efficiency in arsenic removal from drinking water. Iran J Environ Health Sci Eng 2010, 7(3):273-278.
  • [8]Amin MM, Khodabakhshi A, Mozafari M, Bina B, Kheiri S: Removal of Cr(VI) from simulated electrroplating wastewater by magnetite nanoparticles. Environ Engin Manage J 2011, 9(7):921-927.
  • [9]Ghanizadeh G, Ehrampoush MH, Ghaneian MT: Application of iron impregnated activated carbon for removal of arsenic from water. Iran J Environ Health Sci Eng 2010, 7(2):145-156.
  • [10]Maiti A, DasGupta S, Basu JK, De S: Adsorption of arsenite using natural laterite as adsorbent. J Sep Purif Technol 2007, 55:350-359.
  • [11]Dhir B, Kumar R: Adsorption of heavy metals by Salvinia biomass and agricultural residues. Int J Environ Res 2010, 4(3):427-432.
  • [12]Heidari M, Moattar F, Naseri S, Samadi MT, Khorasani N: Evaluation of aluminum-coated pumice as a potential arsenic(V) adsorbent from water resources. Int J Environ Res 2011, 5(2):447-456.
  • [13]Tashauoei HR, Movahedian Attar H, Kamali M, Amin MM, Nikaeen M: Removal of hexavalent chromium CR(VI) from aqueous solutions using surface modified nanozeolite A. Int J Environ Res 2010, 4(3):491-500.
  • [14]Zhang QL, Lin YC, Chenc X, Gao NY: A method for preparing ferric activated carbon composites adsorbents to remove arsenic from drinking. J Hazard Mater 2007, 148:671-678.
  • [15]Tripathy SS, Raichur AM: Enhanced adsorption capacity of activated alumina by impregnation with alum for removal of As(V) from water. J Chem Engin 2007, 5339:1-8.
  • [16]Akbal F: Sorption of phenol and 4-chlorophenol onto pumice treated with cationic surfactant. J Environ Manage 2005, 74:239-244.
  • [17]Elizalde-Gonzalez MP, Mattusch J, Einicke WD, Wennrich R: Sorption on natural solids for arsenic removal. Chem Engin J 2001, 81:187-195.
  • [18]Yang JK, Chang YY, Song KH: Removal of As(III) in a column reactor packed with iron-coated sand and manganese-coated sand. J Hazard Mater 2007, 6828:1-8.
  • [19]Acemioglu B: Batch kinetic study of sorption of methylene blue by perlite. Chem Eng J 2005, 106:73-81.
  • [20]Azizian S: Kinetic models of sorption: a theoretical study. J Colloid Interface Sci 2004, 276:47-52.
  • [21]Mamisahebei S, Jahed Khaniki GR, Torabian A, Nasseri S, Naddafi K: Removal of arsenic from an aqueous solution by pretreated waste tea fungal biomass. Iran J Environ Health Sci Eng 2007, 4(2):85-92.
  • [22]Raichur AM, Panvekar V: Removal of As(V) by adsorption onto mixed rare earth oxides. Sep Sci Technol 2002, 37(5):1095-1108.
  • [23]Loukidou MX, Matis KA, Zouboulis AI, Liakopoulou Kyriakidou M: Removal of As (V) from wastewaters by chemically modified fungal biomass. Water Res 2003, 37:4544-4552.
  • [24]Gaur N, Dhankhar R: Removal of Zn+2 ions from aqueous solution using Anabaena variabilis: Equilibrium and Kinetic studies. Int J Environ Res 2009, 3(4):605-616.
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