Deep investigation on inorganic fraction of atmospheric PM in Mediterranean area by neutron and photon activation analysis

Chemistry Central Journal

Pasquale Avino²  Geraldo Capannesi¹  Maurizio Manigrasso²  Alberto Rosada¹  Mario Vincenzo Russo³ 

[1] UTFISS CATNUC, ENEA, Via Anguillarese 301, Rome 00123, Italy

[2] DIPIA, INAIL settore Ricerca, Certificazione e Verifica, Via IV Novembre 144, Rome 00187, Italy

[3] Department of Environment, Food and Agriculture, University of Molise, Via De Sanctis, Campobasso 86100, Italy

关键词: IPAA;    INAA;    Enrichment factor;    Urban air;    Atmosphere;    PM2.5;    PM10;    Element;   

Others  :  787821
DOI  :  10.1186/1752-153X-7-173

 received in 2013-04-04, accepted in 2013-10-24,  发布年份 2013

【 摘 要 】

Background

Anthropogenic activities introduce materials increasing levels of many dangerous substances for the environmental quality and being hazardous to human health. Major attention has been given to those elements able to alter the environment and endanger human health.

The airborne particulate matter pollutant is considered one of the most difficult task in environmental chemistry for its complex composition and implications complicating notably the behavior comprehension. So, for investigating deeply the elemental composition we used two nuclear techniques, Neutron Activation Analysis and Photon Activation Analysis, characterized by high sensitivity, precision and accuracy. An important task has been devoted to the investigation of Quality Control (QC) and Quality Assurance (QA) of the methodology used in this study.

This study was therefore extended as far back as possible in time (from 1965 until 2000) in order to analyze the trend of airborne concentration of pollutant elements in connection with the industrial and lifestyle growth during the entire period.

Results

Almost all the elements may be attributed to long-range transport phenomena from other natural and/or anthropogenic sources: this behavior is common to all the periods studied even if a very light decreasing trend can be evidenced from 1970 to 2002. Finally, in order to investigate a retrospective study of elements in PM10 and their evolution in relationship with the natural or anthropogenic origins, we have investigated the Enrichment Factors. The study shows the EF trends for some elements in PM10 during four decades.

Conclusions

The two nuclear techniques have allowed to reach elevated sensibility/accuracy levels for determining elements at very low concentrations (trace and ultra-trace levels). The element concentrations determined in this study do not basically show a significant level of attention from a toxicological point of view.

【 授权许可】

   
2013 Avino et al.; licensee Chemistry Central Ltd.

【 图 表 】

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【 参考文献 】

• [1]Dockery DW, Speizer FE, Stram DO, Ware JH, Spengler JD, Ferris BG Jr: Effects of inhalable particles on respiratory health of children. Am Rev Respir Dis 1989, 139(3):587-594.
• [2]Dockey DW, Pope CA: Acute respiratory effects of particulate air pollution. Annu Rev Public Health 1994, 15:107-132.
• [3]Harrison RM, Yin J: Particulate matter in the atmosphere: which particle properties are important for its effects on health? Sci Total Environ 2000, 249(1–3):85-101.
• [4]Cao L, Tian W, Ni B, Zhang Y, Wang P: Preliminary study of airborne particulate matter in a Beijing sampling station by instrumental neutron activation analysis. Atmos Environ 2002, 36(12):1951-1956.
• [5]Avino P, Brocco D, Cecinato A, Lepore L, Balducci C: Carbonaceous components in atmospheric aerosol: measurements, procedures and characterization. Ann Chim (Rome) 2002, 92(4):333-341.
• [6]Avino P, Brocco D: Carbonaceous aerosol in the breathable particulate matter (PM10) in urban area. Ann Chim (Rome) 2004, 94(9–10):647-653.
• [7]Avino P, Capannesi G, Rosada A: Characterization and distribution of mineral content in fine and coarse airborne particle fractions by neutron activation analysis. Toxicol Environ Chem 2006, 88(4):633-647.
• [8]Avino P, Manigrasso M: Vertical distribution of carbonaceous material in urban atmosphere. Fresenius Environ Bull 2006, 15(8b):866-877.
• [9]Avino P, Capannesi G, Rosada A: Heavy metal determination in atmospheric particulate matter by Instrumental Neutron Activation Analysis. Microchem J 2008, 88(2):97-106.
• [10]Manigrasso M, Febo A, Guglielmi F, Ciambottini V, Avino P: Relevance of aerosol size spectrum analysis as support to qualitative source apportionment studies. Environ Pollut 2012, 170:43-51.
• [11]Manigrasso M, Avino P: Fast evolution of urban ultrafine particles: implications for deposition doses in the human respiratory system. Atmos Environ 2012, 51:116-123.
• [12]Agency IAE: Analytical Applications of Nuclear Techniques. Wien: IAEA; 2004.
• [13]Avino P, Santoro E, Sarto F, Violante V, Rosada A: Neutron activation analysis for investigating purity grade of copper, nickel and palladium thin films used in cold fusion experiments. J Radioanal Nucl Chem 2011, 290(2):427-436.
• [14]Capannesi G, Rosada A, Manigrasso M, Avino P: Rare earth elements, thorium and uranium in ores of the North- Latium (Italy). J Radioanal Nucl Chem 2012, 291(1):163-168.
• [15]Segebade C, Weise HP, Lutz GJ: Photon Activation Analysis. Berlin: Walter de Gruyter Inc; 1988.
• [16]Oprea C, Maslov OD, Gustova MV, Oprea IA, Mihul A, Belov AG, Szalanski PJ, Buzguta V: Photoneutron activation analysis applied for environmental researches. Rom Rep Phys 2011, 63(2):348-356.
• [17]Mizera J, Randa Z: Instrumental neutron and photon activation analyses of selected geochemical reference materials. J Radioanal Nucl Chem 2010, 284(1):157-163.
• [18]Campanella L, Crescentini G, Avino P, Moauro A: Determination of macrominerals and trace elements in the alga Spirulina platensis. Analusis 1998, 26:210-214.
• [19]Avino P, Carconi PL, Lepore L, Moauro A: Nutritional and environmental properties of algal products used in healthy diet by INAA and ICP-AES. J Radioanal Nucl Chem 2000, 244(1):247-252.
• [20]Capannesi G, Diaco L, Rosada A, Avino P: Investigation of trace and ultra-trace elements of nutritional and toxicological significance in Italian potable waters by INAA. J Radioanal Nucl Chem 2008, 278(2):353-357.
• [21]Capannesi G, Rosada A, Avino P: Elemental characterization of impurities at trace and ultra-trace levels in metallurgical lead samples by INAA. Microchem J 2009, 93(2):188-194.
• [22]Avino P, Capannesi G, Diaco L, Rosada A: Multivariate analysis applied to trace and ultra-trace elements in Italian potable waters determined by INAA. Curr Anal Chem 2010, 6(1):26-36.
• [23]Capannesi G, Rosada A, Avino P: Radiochemical separation and anti-Compton analysis of Ni, Sn, Te and Zn in lead standard reference materials at ultra-trace levels. Curr Anal Chem 2010, 6(3):217-222.
• [24]Buonanno G, Stabile L, Avino P, Vanoli R: Dimensional and chemical characterization of particles at a downwind receptor site of a waste-to-energy plant. Waste Manag 2010, 30(7):1325-1333.
• [25]Avino P, Capannesi G, Rosada A: Ultra-trace nutritional and toxicological elements in Rome and Florence drinking waters determined by Instrumental Neutron Activation Analysis. Microchem J 2011, 97(2):144-153.
• [26]Avino P, Capannesi G, Manigrasso M, Sabbioni E, Rosada A: Element assessment in whole blood, serum and urine of three Italian healthy sub-populations by INAA. Microchem J 2011, 99(2):548-555.
• [27]Avino P, Capannesi G, Renzi L, Rosada A: Instrumental neutron activation analysis and statistical approach for determining baseline values of essential and toxic elements in hairs of high school students. Ecotoxicol Environ Saf 2013, 92:206-214.
• [28]Randa Z, Frána J, Mizera J, Kucera J, Novák JK, Ulrych J, Belov AG, Maslov OD: Instrumental neutron and photon activation analysis in the geochemical study of phonolitic and trachytic rocks. Geostand Geoanal Res 2007, 31(3):275-283.
• [29]Avino P, Capannesi G, Lopez F, Rosada A: Determination of interesting toxicological elements in PM2.5 by neutron and photon activation analysis. Sci World J 2013., article ID 458793doi: 10.1155/2013/458793
• [30]Locardi E, Sircana S: Distribuzione dell’uranio e del torio nelle vulcaniti quaternarie alcaline del Lazio settentrionale. Rend Soc Mineralog Ital 1967, 23:163-224.
• [31]Locardi E, Mittempergher M: Relationship between some trace elements and magmatic processes. Inter J Earth Sci (Geologische Rundschau) 1967, 57(1):313-334.
• [32]Bergamaschi L, Rizzio E, Valcuvia MG, Verza G, Profumo A, Gallorini M: Determination of trace elements and evaluation of their enrichment factors in Himalayan lichens. Environ Pollut 2002, 120(1):137-144.
• [33]Campanella L, Crescentini G, Avino P: Chemical composition and nutritional evaluation of some natural and commercial food products based on Spirulina. Analusis 1999, 27(6):533-540.
• [34]Bruni F, Manzari C, Filice M, Polosa PL, Colella M, Carmone C, Hambardjieva E, Garcia-Diaz M, Cantatore P, Roberti M: D-MTERF5 is a novel factor modulating transcription in Drosophila mitochondria. Mitochondrion 2012, 12(5):492-499.
• [35]Cardone A, Lopez F, Affortunato F, Busco G, Hofer AM, Mallamaci R, Martinelli C, Colella M, Farinola GM: An aryleneethynylene fluorophore for cell membrane staining. BBA-Biomembranes 2012, 1818(11):2808-2817.
• [36]Currie LA: Limits for qualitative detection and quantitative determination. Application to radiochemistry. Anal Chem 1968, 40(3):586-593.
• [37]Farinha MM, Freitas MC, Almeida SM, Reis MA: Some improvements in air particulate matter analysis by INAA. Radiat Phys Chem 2001, 61(3):659-661.
• [38]Carmo Freitas M, Almeida SM, Reis MA, Oliveira OR: Monitoring trace elements by nuclear techniques in PM10 and PM2.5. Nucl Instrum Methods Phys Res A 2003, 505(1–2):430-434.
• [39]Almeida SM, Reis MA, Freitas MC, Pio CA: Quality assurance in elemental analysis of airborne particles. Nucl Instrum Methods Phys Res, Sect B 2003, 207(4):434-446.
• [40]Djingova R, Arpadjan S, Kuleff I: INAA and flame AAS of various vegetable reference materials. Fresenius J Anal Chem 1991, 339(3):181-186.
• [41]Djingova R, Kuleff I: Instrumental techniques for trace analysis. In Trace Elements - Their Distribution and Effects in the Environment. Edited by Markert B, Friese K. Amsterdam, The Netherlands: Elsevier; 2000:137-185. ISBN-13: 9780444505323
• [42]Di Palo L, Focaccia G, Lo Prato E, Marsili F, Paletti A, Perni M, Prosperi D, Sciuti S, Verri A: Il reattore RC-1 ad 1 MW del Centro Studi Nucleari della Casaccia. Caratteristiche generali e programmi di ricerca. Ener Nuc 1967, 14:659-664.