期刊论文详细信息
Biotechnology for Biofuels
Techno-economic evaluation of 2nd generation bioethanol production from sugar cane bagasse and leaves integrated with the sugar-based ethanol process
Stefano Macrelli1  Johan Mogensen2  Guido Zacchi1 
[1] Department of Chemical Engineering - Lund University, P.O. Box 124, S-22100 Lund, Sweden
[2] Novozymes A/S, Krogshoejvej 36, Bagsvaerd DK-2880, Denmark
关键词: Minimum ethanol selling price;    Production cost;    Techno-economic evaluation;    Simulation;    Bagasse;    Sugar cane;    Lignocellulose;    Advanced biofuel;    Second-generation ethanol;    Bioethanol;   
Others  :  798317
DOI  :  10.1186/1754-6834-5-22
 received in 2011-12-18, accepted in 2012-04-13,  发布年份 2012
PDF
【 摘 要 】

Background

Bioethanol produced from the lignocellulosic fractions of sugar cane (bagasse and leaves), i.e. second generation (2G) bioethanol, has a promising market potential as an automotive fuel; however, the process is still under investigation on pilot/demonstration scale. From a process perspective, improvements in plant design can lower the production cost, providing better profitability and competitiveness if the conversion of the whole sugar cane is considered. Simulations have been performed with AspenPlus to investigate how process integration can affect the minimum ethanol selling price of this 2G process (MESP-2G), as well as improve the plant energy efficiency. This is achieved by integrating the well-established sucrose-to-bioethanol process with the enzymatic process for lignocellulosic materials. Bagasse and leaves were steam pretreated using H3PO4 as catalyst and separately hydrolysed and fermented.

Results

The addition of a steam dryer, doubling of the enzyme dosage in enzymatic hydrolysis, including leaves as raw material in the 2G process, heat integration and the use of more energy-efficient equipment led to a 37% reduction in MESP-2G compared to the Base case. Modelling showed that the MESP for 2G ethanol was 0.97 US$/L, while in the future it could be reduced to 0.78 US$/L. In this case the overall production cost of 1G + 2G ethanol would be about 0.40 US$/L with an output of 102 L/ton dry sugar cane including 50% leaves. Sensitivity analysis of the future scenario showed that a 50% decrease in the cost of enzymes, electricity or leaves would lower the MESP-2G by about 20%, 10% and 4.5%, respectively.

Conclusions

According to the simulations, the production of 2G bioethanol from sugar cane bagasse and leaves in Brazil is already competitive (without subsidies) with 1G starch-based bioethanol production in Europe. Moreover 2G bioethanol could be produced at a lower cost if subsidies were used to compensate for the opportunity cost from the sale of excess electricity and if the cost of enzymes continues to fall.

【 授权许可】

   
2012 Macrelli et al; licensee BioMed Central Ltd.

【 预 览 】
附件列表
Files Size Format View
20140706115823623.pdf 579KB PDF download
Figure 10. 32KB Image download
Figure 2. 54KB Image download
Figure 8. 25KB Image download
Figure 7. 29KB Image download
Figure 6. 29KB Image download
Figure 5. 34KB Image download
Figure 4. 35KB Image download
Figure 3. 39KB Image download
Figure 2. 37KB Image download
Figure 1. 19KB Image download
【 图 表 】

Figure 1.

Figure 2.

Figure 3.

Figure 4.

Figure 5.

Figure 6.

Figure 7.

Figure 8.

Figure 2.

Figure 10.

【 参考文献 】
  • [1]MAPA [http:/ / www.agricultura.gov.br/ comunicacao/ noticias/ 2009/ 08/ especial-dados-da-agroenergia-estao -disponiveis-no-portal-do-ministeri o-da-agricultura] webcite
  • [2]Lynd LR, Van Zyl WH, McBride JE, Laser M: Consolidated bioprocessing of cellulosic biomass: an update. Curr Opin Biotechnol 2005, 16:577-583.
  • [3]CGEE: Bioetanol combustível: uma oportunidade para o Brasil. Brasilia: CGEE; 2009.
  • [4]Bajay SV, Nogueira LAH, de Sousa FJR: Ethanol in the Brazilian energy matrix. In Ethanol and bioelectricity: sugarcane in the future energy matrix. Edited by Unica. Sao Paulo: Unica; 2011:260-308.
  • [5]CGEE: B: Sugarcane-based bioethanol: energy for sustainable development. Rio de Janeiro: BNDES; 2008.
  • [6]Macedo IC, Seabra JEA, Silva JEAR: Green house gases emissions in the production and use of ethanol from sugarcane in Brazil: the 2005/2006 averages and a prediction for 2020. Biomass Bioenergy 2008, 32:582-595.
  • [7]MAPA [http:/ / www.agricultura.gov.br/ politica-agricola/ noticias/ 2011/ 01/ safra-20102011-de-cana-e-recorde] webcite
  • [8]Portaria n.678/2011 [http:/ / www.in.gov.br/ visualiza/ index.jsp?data=01/ 09/ 2011&jornal=1&pagina=3&totalArquivo s=212] webcite
  • [9]SECEX/SDP [http://www.mdic.gov.br] webcite
  • [10]MAPA [http:/ / www.agricultura.gov.br/ politica-agricola/ noticias/ 2011/ 08/ governoadotara-medidas-de-incentivo -a-producao] webcite
  • [11]Cardona CA, Quintero JA, Paz IC: Production of bioethanol from sugarcane bagasse: Status and perspectives. Bioresour Technol 2010, 101:4754-4766.
  • [12]Ensinas AV, Arnao JHS, Nebra SA: Increasing energetic efficiency in sugar, ethanol, and electricity producing plants. In Sugarcane bioethanol: R&D for productivity and sustainability. 1st edition. Edited by Cortez LAB. Sao Paulo: Editora Edgard Blucher Ltda; 2010:583-600.
  • [13]Hahn-Hägerdal B, Galbe M, Gorwa-Grauslund MF, Lidén G, Zacchi G: Bio-ethanol - the fuel of tomorrow from the residues of today. Trends Biotechnol 2006, 24:549-556.
  • [14]Galbe M, Sassner P, Wingren A, Zacchi G: Process engineering economics of bioethanol production. 2007, 108:303-327.
  • [15]Hassuani SJ, Da Silva JEAR, Neves JLM: Sugarcane trash recovery alternatives for power generation. Zuckerindustrie 2005, 130:781-786.
  • [16]Franco HCJ, Magalhãs PSG, Cavalett O, Cardoso TF, Braunbeck OA, Bonomi A, Trivelin PCO: How much trash to removal from sugarcane field to produce bioenergy? [abstract]. Proceedings Brazilian BioEnergy Science and Technology; Campos do Jordão 2011.
  • [17]Mosier N, Wyman C, Dale B, Elander R, Lee YY, Holtzapple M, Ladisch M: Features of promising technologies for pretreatment of lignocellulosic biomass. Bioresour Technol 2005, 96:673-686.
  • [18]Galbe M, Zacchi G: A review of the production of ethanol from softwood. Appl Microbiol Biotechnol 2002, 59:618-628.
  • [19]Tao L, Aden A, Elander RT, Pallapolu VR, Lee YY, Garlock RJ, Balan V, Dale BE, Kim Y, Mosier NS, et al.: Process and technoeconomic analysis of leading pretreatment technologies for lignocellulosic ethanol production using switchgrass. Bioresour Technol 2011, 102:11105-11114.
  • [20]Kumar D, Murthy GS: Impact of pretreatment and downstream processing technologies on economics and energy in cellulosic ethanol production. Biotechnol Biofuels 2011, 4:27. BioMed Central Full Text
  • [21]Piccolo C, Bezzo F: A techno-economic comparison between two technologies for bioethanol production from lignocellulose. Biomass Bioenergy 2009, 33:478-491.
  • [22]Wingren A, Galbe M, Zacchi G: Techno-economic evaluation of producing ethanol from softwood: Comparison of SSF and SHF and identification of bottlenecks. Biotechnol Prog 2003, 19:1109-1117.
  • [23]Sassner P, Galbe M, Zacchi G: Techno-economic evaluation of bioethanol production from three different lignocellulosic materials. Biomass Bioenergy 2008, 32:422-430.
  • [24]Zimbardi F, Ricci E, Braccio G: Technoeconomic study on steam explosion application in biomass processing. Appl Biochem Biotechnol-Part A Enzyme Eng Biotechnol 2002, 98-100:89-99.
  • [25]Lynd LR, Elander RT, Wyman CE: Likely features and costs of mature biomass ethanol technology. Appl Biochem Biotechnol-Part A Enzyme Eng Biotechnol 1996, 57-58:741-761.
  • [26]Dias MOS, Ensinas AV, Nebra SA, Maciel Filho R, Rossell CEV, Maciel MRW: Production of bioethanol and other bio-based materials from sugarcane bagasse: Integration to conventional bioethanol production process. Chem Eng Res Des 2009, 87:1206-1216.
  • [27]Seabra JEA, Tao L, Chum HL, Macedo IC: A techno-economic evaluation of the effects of centralized cellulosic ethanol and co-products refinery options with sugarcane mill clustering. Biomass Bioenergy 2010, 34:1065-1078.
  • [28]Junqueira TL, Dias MOS, Jesus CDF, Mantelatto PE, Cunha MP, Cavalett O, Filho RM, Rossell CEV, Bonomi A: Simulation and evaluation of autonomous and annexed sugarcane distilleries. Chemical Engineering Transactions 2011, 25:941-946.
  • [29]Wingren A, Galbe M, Roslander C, Rudolf A, Zacchi G: Effect of reduction in yeast and enzyme concentrations in a simultaneous-saccharification-and-fermentation-based bioethanol process: technical and economic evaluation. Appl Biochem Biotechnol- Part A Enzyme Eng Biotechnol 2005, 122:485-499.
  • [30]Ensinas AV, Nebra SA, Lozano MA, Serra LM: Analysis of process steam demand reduction and electricity generation in sugar and ethanol production from sugarcane. Energy Conversion Manage 2007, 48:2978-2987.
  • [31]Wingren A, Galbe M, Zacchi G: Energy considerations for a SSF-based softwood ethanol plant. Bioresour Technol 2008, 99:2121-2131.
  • [32]Ensinas AV, Nebra SA, Lozano MA, Serra L: Design of evaporation systems and heaters networks in sugar cane factories using a thermoeconomic optimization procedure. Int J Thermodyn 2007, 10:97-105.
  • [33]Dias MOS, Junqueira TL, Filho RM, Maciel MRW, Rossell CEV, Atala DIP: Optimization of bioethanol distillation process evaluation of different configurations of the fermentation process. Book Optimization of bioethanol distillation process evaluation of different configurations of the fermentation process 27:1893-1898. City; 2009:1893-1898
  • [34]Sassner P, Zacchi G: Integration options for high energy efficiency and improved economics in a wood-to-ethanol process. Biotechnol Biofuels 2008, 1:4. BioMed Central Full Text
  • [35]Franceschin G, Zamboni A, Bezzo F, Bertucco A: Ethanol from corn: a technical and economical assessment based on different scenarios. Chem Eng Res Des 2008, 86:488-498.
  • [36]Dias MOS, Cunha MP, Jesus CDF, Rocha GJM, Pradella JGC, Rossell CEV, Maciel Filho R, Bonomi A: Second generation ethanol in Brazil: can it compete with electricity production? Bioresour Technol 2011, 102:8964-8971.
  • [37]CaneBioFuel - webpage [http://www.canebiofuel.com] webcite
  • [38]CEPEA [http://www.cepea.esalq.usp.br] webcite
  • [39]CaneBioFuel - Compositional analysis [http://www.canebiofuel.com/files/DeliveryReport1.2.pdf] webcite
  • [40]CaneBioFuel - Residues analysis [http://www.canebiofuel.com/files/DeliveryReport5.1.pdf] webcite
  • [41]Wooley RJ, Putsche V: Development of an ASPEN PLUS Physical Property Database for Biofuels Components. Golden, CO: NREL; 1996. Report MP-425-20685
  文献评价指标  
  下载次数:171次 浏览次数:44次