Synthesis of 1, 5, 6, 10 _ Tetranitrodecahydro - [1, 4] Diazepino [2, 3-b] Diazepine and Its Thermal Property Research

2018 5th International Conference on Advanced Composite Materials and Manufacturing Engineering

Li, Sainan^1 ; Meng, Zihui^1 ; Xu, Zhibin^1

School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing

100081, China^1

关键词: Apparent activation energy;    Diazepine;    DTA methods;    Hydrolysis reaction;    Kissinger methods;    Peak temperatures;    Thermodynamic parameter;   

Others  :  https://iopscience.iop.org/article/10.1088/1757-899X/394/2/022014/pdf
DOI  :  10.1088/1757-899X/394/2/022014

来源: IOP

【 摘 要 】

1, 5, 6, 10 - tetranitrodecahydro- [1, 4] diazepino [2, 3-b] diazepine (TNDP) was synthesized using tetranitroglycoluril as the starting material by hydrolysis reaction and condensation. The thermo stability of TNDP was studied by DSC and TG-DTA methods, and the thermodynamic parameters were calculated by Kissinger method and related formulas. The results showed that TNDP was thermal stable and the peak temperature of DSC was 311.76 °C. The apparent activation energy was 162.70 kJ/mol. In general, TNDP is a kind of good performance energetic materials.