Effect of Temperature to Adsorption Capacity and Coefficient Distribution on Rare Earth Elements Adsorption (Y, Gd, Dy) Using SIR

12th Joint Conference on Chemistry

Aziz, N.^1 ; Mindaryani, A.^1 ; Supranto^1 ; Taftazani, A.^2 ; Biyantoro, D.^2

Chemical Engineering-Universitas Gadjah Mada, Indonesia^1

Centre for Science and Accelerator Technology-National Nuclear Energy Agency of Indonesia, Yogyakarta, Indonesia^2

关键词: Adsorption capacities;    Coefficient distribution;    Di(2-ethylhexyl)phosphate;    Effect of temperature;    Equilibrium equation;    Equilibrium modeling;    Increase the purities;    Temperature variation;   

Others  :  https://iopscience.iop.org/article/10.1088/1757-899X/349/1/012041/pdf
DOI  :  10.1088/1757-899X/349/1/012041

来源: IOP

【 摘 要 】

The use of REE like element of Yttrium (Y) as a superconducting material requires a purity of more than 90%, so it needs to increase the purity of Y from the settling process. The purpose of this research is to study the separation process of REE that is Y, Gd, Dy elements from REE hydroxide (REE(OH)3) using SIR method are consisting of Amberlite XAD-16 resin impregnated with Di-(2-ethylhexyl) phosphate ( D2EHPA) and Tributyl Phosphate (TBP) and determine the isotherm model on REE adsorption and determine the kinetic model of pseudo adsorption reaction. This research was started by activating XAD-16 resin and is mixed with TBP-D2EHPA solvents so it will form SIR, then it is conducted on variation of SIR composition, temperature variation of adsorption process, determination of equilibrium equation and kinetic sorption occurring in SIR adsorption based on experimental data of liquid concentration as function of time. Based on the calculation result, the most effective SIR composition for REE separation is 0.75 g, the equilibrium equation for Y, Gd and Dy follows the Henry equilibrium model and the pseudo kinetic model of the reaction order Y, Gd, and Dy is followed by the pseudo reaction of order 2 The result of separation of LTJ with SIR is said to be effective from another method because purity is obtained that is 96.73% and qualify as a super conductor material.