Influence of CuO nanoparticle on palm oil based alkyd resin preparation and its antimicrobial activity

2017 5th International Conference on Mechanical Engineering, Materials Science and Civil Engineering

机械制造;材料科学;土木建筑工程

Ruey Ong, Huei^1 ; Khan, Md. Maksudur Rahman^2 ; Ramli, Ridzuan^3 ; Shein Hong, Chi^2 ; Mohd Yunus, Rosli^2

Faculty of Engineering and Technology, DRB-HICOM University of Automotive Malaysia, Pekan, Pahang

26607, Malaysia^1

Faculty of Chemical and Natural Resources Engineering, Universiti Malaysia Pahang, Lebuhraya Tun Razak, Pahang, Gambang

26300, Malaysia^2

Malaysian Palm Oil Board (MPOB), Persiaran Institusi, No. 6, Bandar baru bangi, Selangor, Kajang

43000, Malaysia^3

关键词: Anti-microbial activity;    CuO nanoparticles;    Differential scanning calorimeters;    Ester linkages;    Phthalic anhydrides;    Polyesterification;    Reaction conditions;    Resin samples;   

Others  :  https://iopscience.iop.org/article/10.1088/1757-899X/324/1/012027/pdf
DOI  :  10.1088/1757-899X/324/1/012027

来源: IOP

【 摘 要 】

An alkyd resin has been synthesized from palm oil that reacted with glycerol and phthalic anhydride by alcoholysis-polyesterification process and co-catalyzed by CuO nanoparticle. The CuO nanoparticle was pre-prepared in the glycerol via sol gel method, which creates a new reaction condition for resin preparation. The resins were characterized by fourier transform infrared spectroscopy (FTIR), where a new ester linkage bond (C-O-C) was noticed for resin sample. The antimicrobial activity and the curing behaviour of the resin were determined by Kirby-Bauer and differential scanning calorimeter technique. It was found that, the addition of CuO speeded up the reaction rate and played antimicrobial role. Moreover, it shortens the reaction time of alcoholysis and polyesterification process.