Homogenization Effect on Nanostructure and Conductivity of Polyaniline Nanofibre Synthesis by Mini-Emulsion Polymerization Technique

3rd International Conference on Smart Material Research

Mohammad, M.^1 ; Kamarudin, S.^1 ; Mohamed, N.H.^2 ; Asim, N.^1 ; Sopian, K.^1

Solar Energy Research Institute (SERI), Universiti Kebangsaan Malaysia, Bangi, Selangor

43600, Malaysia^1

Malaysia Nuclear Agency (Nuclear Malaysia), Bangi, Selangor, Kajang

43600, Malaysia^2

关键词: Aniline monomers;    Crystalline nature;    Electrical conductivity;    Hall effect measurement;    Mini-emulsion polymerization;    Morphological properties;    Nano-structured;    Optimum speed;   

Others  :  https://iopscience.iop.org/article/10.1088/1757-899X/293/1/012012/pdf
DOI  :  10.1088/1757-899X/293/1/012012

来源: IOP

【 摘 要 】

Nanofibre polyaniline (n-PANI) was synthesized by mini-emulsion polymerization technique between aniline monomer and ammonium persulfate as an oxidant using homogenizer. The synthesis was performed by optimizing mixing speed from 10,000 to 30,000 rpm and time reaction between 0.5 to 24 hours at fixed monomer to oxidant molar ratio 4:1. An attempt has been made to investigate on how the speed of homogenizer affects the size and conductivity of n-PANI. The formation of n-PANI chain was confirmed by Fourier transform infrared spectroscopy (FTIR). The X-ray diffraction (XRD) spectra revealed PANI crystalline nature. Hall effect measurement used indicated that the electrical conductivity of n-PANI is increased with homogenizer speed from 5.2 to 17.5 Scm-1. The morphological properties of n-PANI performed by scanning electron microscopy (SEM) show the decreasing size of n-PANI from 50-60 nm to 20-30 nm with the increment homogenizer speed. This study indicated the optimum speed parameter of homogenizer play a role in reducing the nanostructured size and thus, increasing the electrical conductivity of n-PANI.