Copolymerization of ethylene with polar monomer by α - diimine nickel complex

2017 2nd International Seminar on Advances in Materials Science and Engineering

Han, Yiqin^1 ; Zhang, Danfeng^1

Shanghai Key Laboratory of Advanced Polymeric Materials, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai

200237, China^1

关键词: Ethyl acrylates;    Ethylene pressure;    Experimental conditions;    High-temperature NMR;    Methylaluminoxane;    Nickel catalyst;    Polymerization temperature;    Polymerization time;   

Others  :  https://iopscience.iop.org/article/10.1088/1757-899X/231/1/012140/pdf
DOI  :  10.1088/1757-899X/231/1/012140

来源: IOP

【 摘 要 】

Copolymerization of ethylene and ethyl acrylate was carried out by α-diimine nickel catalyst [ArN=CH-CH=NAr]NiBr2 (Ar = 2,6-C6H3(CH3)2) in the presence of methylaluminoxane (MAO). The effects of experimental conditions in which mole ratio of Al/Ni, concentration of polar monomer, polymerization temperature, ethylene pressure and polymerization time varied on ethylene-ethyl acrylate copolymerization were investigated. The structures of the obtained copolymers were characterized by high-temperature NMR and FT-IR. It was found that Al/Ni mole ratio was 1000, the concentration of ethyl acrylate was 10 mmol/L, the polymerization temperature was 30 °C, the ethylene pressure was 10 atm, the polymerization time was 4 h, the molecular weight of the polymer and the incorporation of ethyl acrylate in the copolymer reached the good result.