Magnesium stearine production via direct reaction of palm stearine and magnesium hydroxide

29th Symposium of Malaysian Chemical Engineers 2016

Pratiwi, M.^1 ; Ylitervo, P.^2 ; Pettersson, A.^2 ; Prakoso, T.^1 ; Soerawidjaja, T.H.^1

Department of Chemical Engineering, Institut Teknologi Bandung, West Java, Bandung

40132, Indonesia^1

Swedish Centre for Resource Recovery, University of Boras, Boras

50332, Sweden^2

关键词: Decomposition temperature;    Energy dispersive x-ray;    Magnesium hydroxide;    Magnesium stearate;    Microwave plasma;    Operation process;    Renewable alternative energy sources;    Thermogravimetry analysis;   

Others  :  https://iopscience.iop.org/article/10.1088/1757-899X/206/1/012026/pdf
DOI  :  10.1088/1757-899X/206/1/012026

来源: IOP

【 摘 要 】

The fossil oil production could not compensate with the increase of its consumption, because of this reason the renewable alternative energy source is needed to meet this requirement of this fuel. One of the methods to produce hydrocarbon is by decarboxylation of fatty acids. Vegetable oil and fats are the greatest source of fatty acids, so these can be used as raw material for biohydrocarbon production. From other researchers on their past researchs, by heating base soap from divalent metal, those metal salts will decarboxylate and produce hydrocarbon. This study investigate the process and characterization of magnesium soaps from palm stearine by Blachford method. The metal soaps are synthesized by direct reaction of palm stearine and magnesium hydroxide to produce magnesium stearine and magnesium stearine base soaps at 140-180°C and 6-10 bar for 3-6 hours. The operation process which succeed to gain metal soaps is 180°C, 10 bar, for 3-6 hours. These metal soaps are then compared with commercial magnesium stearate. Based on Thermogravimetry Analysis (TGA) results, the decomposition temperature of all the metal soaps were 250°C. Scanning Electron Microscope with Energy Dispersive X-ray (SEM-EDX) analysis have shown the traces of sodium sulphate for magnesium stearate commercial and magnesium hydroxide for both type of magnesium stearine soaps. The analysis results from Microwave Plasma-Atomic Emission Spectrometry (MP-AES) have shown that the magnesium content of magnesium stearine approximate with magnesium stearate commercial and lower compare with magnesium stearine base soaps. These experiments suggest that the presented saponification process method could produced metal soaps comparable with the commercial metal soaps.