Synthesis, Investigation on Structural and Magnetic Behaviors of Spinel M-Ferrite [M = Fe; Zn; Mn] Nanoparticles from Iron Sand

4th International Conference on Advanced Materials Science and Technology

Bahtiar, S.^1 ; Taufiq, A.^1,2 ; Sunaryono^1,2 ; Hidayat, A.^1,2 ; Hidayat, N.^1,2 ; Diantoro, M.^1,2 ; Mufti, N.^1,2 ; Mujamilah^3

Department of Physics, Faculty of Mathematics and Natural Sciences, Universitas Negeri Malang, State University of Malang, Jl. Semarang 5, Malang

65145, Indonesia^1

Center for Minerals and Advanced Materials, Faculty of Mathematics and Natural Sciences, Universitas Negeri Malang, State University of Malang, Jl. Semarang 5, Malang

65145, Indonesia^2

Center for Technology of Nuclear Industry Materials, National Nuclear Energy Agency (BATAN), Kawasan Puspiptek Serpong, Tangerang

15314, Indonesia^3

关键词: Ferrite nanoparticles;    Fourier transform infra red (FTIR) spectroscopy;    M-ferrite [M = Fe;    Zn;    Mn];    Magnetization curves;    Sonochemical;    Superparamagnetic behavior;    Vibration sample magnetometers;    X ray diffractometers;   

Others  :  https://iopscience.iop.org/article/10.1088/1757-899X/202/1/012052/pdf
DOI  :  10.1088/1757-899X/202/1/012052

来源: IOP

【 摘 要 】

Spinel M-ferrite [M = Fe; Zn; Mn] nanoparticles were prepared from iron sand using a coprecipitation-sonochemical approach. The purified Fe3O4from iron sand, ZnCl2and MnCl2.4H2O, HCl, and NH4OH were used as raw materials. X-Ray Diffractometer (XRD), Fourier Transform Infra-Red (FTIR) spectroscopy, Transmission Electron Microscopy (TEM), and Vibration Sample Magnetometer (VSM) were employed to characterize the crystal structure, functional groups, particle size, morphology, and magnetic behavior of the prepared samples, respectively. From the XRD data analysis, M-ferrite particles exhibited a single phase in spinel structure. Furthermore, the M-ferrite particle increased their lattice parameter and crystal volume tracking the metallic-ionic radii of M. The particle size of the M-ferrites particles varied with M, whereas the biggest and lowest were for Zn and Mn, respectively. Based on the magnetization curve, the M-ferrite nanoparticles tended to perform a superparamagnetic behavior and their saturation magnetization as a function of their M ion and particle size.