Preparation of Biodiesel from Microalgae and Palm Oil by Direct Transesterification in a Batch Microwave Reactor

3rd International Conference on Science & Engineering in Mathematics, Chemistry and Physics 2015

数学;化学;物理学

Marwan^1 ; Suhendrayatna^1 ; Indarti, E.^2

Chemical Engineering Department, Faculty of Engineering, Syiah Kuala University, Darussalam, Banda Aceh

23111, Indonesia^1

Agricultural Product Technology Department, Faculty of Agriculture, Syiah Kuala University, Darussalam, Banda Aceh

23111, Indonesia^2

关键词: Chlorella sp;    Conventional heating methods;    Conventional methods;    Direct transesterification;    Equilibrium conversion;    Ethanolysis;    Fatty acid ethyl ester;    Micro-algae;   

Others  :  https://iopscience.iop.org/article/10.1088/1742-6596/622/1/012040/pdf
DOI  :  10.1088/1742-6596/622/1/012040

来源: IOP

【 摘 要 】

The present work was aimed to study the so-called direct transesterification of microalgae lipids to biodiesel in a batch microwave reactor. As a comparison, preparation of palm oil to biodiesel by alkaline catalyzed ethanolysis was also carried out. Palm oil biodiesel was recovered close to an equilibrium conversion (94-96% yield) under microwave heating for at least 6 min, while the conventional method required more than 45 minutes reaching the same yield. A very short reaction time suggests the benefit of microwave effect over conventional heating method in making biodiesel. FTIR analysis revealed the presence of fatty acid ethyl esters with no undesired chemical groups or compounds formed due to local heat generated by microwave effect, thus the conversion only followed transesterification route. Oil containing microalgae of Chlorella sp. isolated from the local brackish water pond was used as a potential source of biodiesel. High yield of biodiesel (above 0.6 g/g of dried algae) was also attainable for the direct transesterification of microalgae in the microwave reactor. Effect of water content of the algae biomass became insignificant at 11.9%(w/w) or less, related to the algae biomass dried for longer than 6 h. Fast transesterification of the algal oil towards equilibrium conversion was obtained at reaction time of 6 min, and at longer times the biodiesel yield remains unchanged. FAME profile indicates unsaturated fatty acids as major constituents. It was shown that microwave irradiation contributes not only to enhance the transeseterification, but also to assist effective release of fatty acid containing molecules (e.g. triacylglycerol, free fatty acids and phospholipids) from algal cells.